Systematizing Microbial Bioplastic Production for Developing Sustainable Bioeconomy: Metabolic Nexus Modeling, Economic and Environmental Technologies Assessment.

The excessive usage of non-renewable resources to produce plastic commodities has incongruously influenced the environment's health. Especially in the times of COVID-19, the need for plastic-based health products has increased predominantly. Given the rise in global warming and greenhouse gas emissions, the lifecycle of plastic has been established to contribute to it significantly. Bioplastics such as polyhydroxy alkanoates, polylactic acid, etc. derived from renewable energy origin have been a magnificent alternative to conventional plastics and reconnoitered exclusively for combating the environmental footprint of petrochemical plastic. However, the economically reasonable and environmentally friendly procedure of microbial bioplastic production has been a hard nut to crack due to less scouted and inefficient process optimization and downstream processing methodologies. Thereby, meticulous employment of computational tools such as genome-scale metabolic modeling and flux balance analysis has been practiced in recent times to understand the effect of genomic and environmental perturbations on the phenotype of the microorganism. In-silico results not only aid us in determining the biorefinery abilities of the model microorganism but also curb our reliance on equipment, raw materials, and capital investment for optimizing the best conditions. Additionally, to accomplish sustainable large-scale production of microbial bioplastic in a circular bioeconomy, extraction, and refinement of bioplastic needs to be investigated extensively by practicing techno-economic analysis and life cycle assessment. This review put forth state-of-the-art know-how on the proficiency of these computational techniques in laying the foundation of an efficient bioplastic manufacturing blueprint, chiefly focusing on microbial polyhydroxy alkanoates (PHA) production and its efficacy in outplacing fossil based plastic products.

Bioplastics, biocomposites and biobased polymers-kications and innovative approaches for sustainability

Increased environmental hazard caused by plastics and other nonbiodegradable polymers are a major issue of international concern and there are continued efforts for development of items which are eco-friendly and cost-effective. Bioplastic, biocomposites, and biobased polymeric products are the most innovative eco-friendly materials developed to overcome the limitations of presently available products. In spite of the post-COVID-19 implications on the economy the bioplastics market is anticipated to reach USD 5643 million by 2028 from the present approximately 4000 million indicating a CAGR, of 5.9%. Similarly, biocomposites market too is expected to reach up to USD 36.76 billion by next 2 years. In view of compliances and effects toward sustainable development goals (SDGs), we need to increase awareness among the masses with reference to sustainable and cost-effective products. The novel materials and translational science may also contribute in development of packaging solutions, biomateriais, medical implants with desired properties and minimal toxicological effects upon administration. The ISO 17088:2021, European Union, ASTM D6400-04 etc. specification need to be enforced in view of regulatory requirements and infrastructure to be standardized, validated as well as established for monitoring and effective management. The innovative and sustainable products have an array of application ranging from agriculture and food packaging to automotive industry. These materials are not only a boon to solve the current environmental crisis but also they are highly versatile in their application, which makes them the choice material. The futuristic smart and intelligent technologies are a ray of hope for better future, sustainable holistic developments in terms of environmental safety. © 2023 Scrivener Publishing LLC. All rights reserved.

RESÍDUOS PLÁSTICOS E SUSTENTABILIDADE: REFLEXOS E IMPACTOS DA PANDEMIA DE COVID-19 NO CONTEXTO SOCIOCULTURAL E AMBIENTAL

Objetivo: O artigo buscou analisar os impactos e reflexos da pandemia de COVID-19 na gestão dos resíduos plásticos. Referencial teórico: A preocupação com a COVID-19 resultou em diversas medidas protetivas, como a determinação do uso de EPIs e restrições de circulação nos centros urbanos. Essas mudanças também impactaram padrões de geração e gestão de resíduos sólidos, especialmente de resíduos plásticos, cujos reflexos negativos nos aspectos socioambientais podem emergir, dado seu descarte inadequado. Método: Foi realizada uma revisão sistemática de literatura, nas bases de dados Scopus, Sage e Web of Science, com utilização do Methodi Ordinatio. Ao total, 22 estudos foram selecionados, compondo o portfólio de pesquisa. Resultados e conclusão: Os resultados demonstraram uma maior concentração de estudos que relacionam os resíduos plásticos nas regiões costeiras, especialmente provenientes de EPIs, e a poluição por microplásticos. Além disso, há uma preocupação com a geração de resíduos de embalagens pela alteração nos padrões de consumo, com o aumento da procura por serviços de e-commerce e delivery. Além de uma preocupação ambiental, destaca-se um problema de ordem social à longo prazo, devido à quebra de padrões de comportamentos sustentáveis na utilização de plástico descartável. Implicações da pesquisa: Soluções são propostas no sentido de utilização de plásticos biodegradáveis, reutilização de EPIs e novas tecnologias de tratamento de resíduos, além da mudança no comportamento social. Originalidade/valor: De um modo geral, o estudo fornece insights e promove reflexões sobre os desafios enfrentados no gerenciamento de resíduos plásticos durante a pandemia de COVID-19.Alternate :Purpose: The article aims to analyze the impacts and reflections of the COVID-19 pandemic on plastic waste management. Theoretical Framework: The concern with COVID-19 resulted in several protective measures, such as the use of PPE and movement restrictions in urban centers. These changes also affected patterns of generation and management of solid waste, especially plastic waste, whose negative effects on socio-environmental aspects may emerge due to its inadequate disposal. Method: We conducted a systematic literature review in the databases Scopus, Sage and Web of Science, employing the Methodi Ordinatio. The review selected 22 studies to compose the research portfolio. Results and conclusion: The results showed a higher concentration of studies on plastic waste in coastal regions, especially from PPE and microplastic pollution. Moreover, there is a concern with the generation of packaging waste by shifting consumption patterns with the increased demand for e-commerce and delivery services. Besides an environmental concern, a long-term social problem stands out regarding the breaking of sustainable behavior patterns in using disposable plastic. Research implications: We propose solutions involving the use of biodegradable plastics, reuse of PPE, and new waste treatment technologies, besides changes in social behavior. Originality/Value: Overall, the study provides insights and promotes reflections on the challenges faced in managing plastic waste during the COVID-19 pandemic.

Biopolymeric sustainable materials and their emerging applications

Advancements in polymer science and engineering have helped the scientific community to shift its attention towards the use of environmentally benign materials for reducing the environmental impact of conventional synthetic plastics. Biopolymers are environmentally benign, chemically versatile, sustainable, biocompatible, biodegradable, inherently functional, and ecofriendly materials that exhibit tremendous potential for a wide range of applications including food, electronics, agriculture, textile, biomedical, and cosmetics. This review also inspires the researchers toward more consumption of biopolymer-based composite materials as an alternative to synthetic composite materials. Herein, an overview of the latest knowledge of different natural- and synthetic-based biodegradable polymers and their fiber-reinforced composites is presented. The review discusses different degradation mechanisms of biopolymer-based composites as well as their sustainability aspects. This review also elucidates current challenges, future opportunities, and emerging applications of biopolymeric sustainable composites in numerous engineering fields. Finally, this review proposes biopolymeric sustainable materials as a propitious solution to the contemporary environmental crisis. © 2022 Elsevier Ltd.

Spent coffee grounds: An intriguing biowaste reinforcement of thermoplastic starch with potential application in green packaging

With respect to the explosion of single-use plastic packaging consumption during the COVID-19 pandemic, environmentally friendly substitutes are critically needful for sustainable development. Therefore, the present work focuses on the functional properties of bioplastic blends prepared through hot compressing molding of thermoplastic starch (TPS) and spent coffee grounds (SCG) in different ratios (0%–20% SCG) as the potential features of SCG were extensively employed in biocomposites for the first time. The insertion of dark brown SCG into TPS hindered UV transmission by 100% at 320 nm and 99.2% at 400 nm. Moreover, the samples with 15% and 20% SCG induced a surge in radical scavenging activity from 7.95% to over 92% at a concentration of 0.1 g/ml owing to the rich source of antioxidants in SCG. The lignin component and high carbon content also improved the thermal performance of TPS/SCG blends, enhancing thermal stability, delaying onset and maximum degradation temperatures, and achieving the HB rating in the UL-94 test. Compared to a pure TPS matrix, TPS blends incorporating up to 10% SCG exhibited improvement in elastic modulus without deterioration of tensile strength. © 2022 Society of Plastics Engineers.

Smart Material Choice: The Importance of Circular Design Strategy Applications for Bio-Based Food Packaging Preproduction and End-of-Life Life Cycle Stages

This article provides a systematic literature review on the integrated approach of bio-based plastic food packaging in a circular economy. It focuses on the following key areas: (1) the role of bio-based plastic food packaging in a circular product design strategy and material choice in the preproduction life cycle stage;(2) the role of bio-based plastic food packaging in circular resource management systems and the product disposal life cycle stage;and (3) an optimal bio-based plastic food packaging application in regard to prioritising end-of-life treatment. While there are dedicated publications on the role of packaging in a circular economy, circular packaging design, packaging waste management, and bio-origin plastic applications in food packaging, this article aims to provide an integrated review and recommendations on the best bio-based plastic food packaging material selection, applications based on a circular economy, and scenarios on waste/resource management that prioritise end-of-life treatment. Three of the current most popular bio-based plastic materials in the flexible and rigid food packaging categories were selected: starch blends, bio-PE, and PLA for flexible food packaging and PLA, bio-PET, and bio-PE for rigid packaging. This article highlights the fact that a smart material choice in the circular design strategy is a key factor that has a direct impact on the last packaging life cycle stage (disposal), and concludes that bio-based plastic materials are a way to close the food packaging loop, either by re-use or recycling. This article also provides recommendations on the best bio-based plastic food packaging material selection, and applications based on the circular economy and waste management that prioritise end-of-life treatment. The research results indicate a research niche for the application of re-usable biodegradable materials in food packaging. The findings of this research allow product designers and packaging companies to advance the understanding of the most efficient bio-based plastic food packaging integration into the circular economy via decision making of product material choice and end-of-life treatment. Based on the results of this article, scholars can develop new themes for further research.

Bio-Based Materials Riding the Wave of Sustainability: Common Misconceptions, Opportunities, Challenges and the Way Forward

Solid waste disposal, particularly of plastic and rubber, significantly impacts the environment and human health;thus, encouraging consumers to u sustainable alternatives is essential to ensure a resilient future. In recent decades, bio-based material research has primarily focused on bioplastics and, accordingly, current knowledge of alternative sustainable materials (such as biorubber) is fragmented, with consumer misconceptions posing a key challenge. This paper provides a comprehensive overview of the fundamentals of bio-based materials, in addition to common misconceptions about them. The findings of a public survey that aimed to assess consumers’ attitudes towards, as well as their awareness and perceptions of, conventional and sustainable alternative materials, particularly oxo-biodegradable rubbers, are also reported in this paper. Despite their unfamiliarity with the terms ‘bio-based’ and ‘oxo-biodegradable’, most respondents had a positive view of bio-based products and expressed an interest in reducing their use of conventional products in favour of sustainable alternatives. The results also revealed that consumers are willing to spend more on sustainable alternatives because they are aware of the environmental issues associated with solid waste. This study provides new insights into knowledge gaps and challenges that must be addressed to promote the prudent use of sustainable materials in a fast-changing world.

Study on the Effect of Bio-Based Materials’ Natural Degradation in the Environment

The article presents an analysis of the impact of bio-based materials on the environment, with a special focus on polylactic acid (PLA), as it is considered one of the most popular bioplastics in the market. The results show that there are several factors that must be taken into account when choosing the best end-of-life option for this type of material, in agreement with the newly introduced concept of the circular economy, according to the physical–chemical analysis obtained at the end of this study. The ecotoxicity tests showed that all tested materials (PLA spoon, PLA filament, b2w technology bag and cocoa paper tray) could be suitable for incineration with energy recovery without producing dioxines during combustion (chlorine content in all tested materials was below 1.00% w/w). It was also determined that PLA was the material with the highest potential for energy recovery since it presented the highest calorific value and highest carbon content (18.73 MJ/kg and 52.23%, respectively). The biodegradation rate of the different bio-based materials was also tested under different environments during three months, with Baltic Sea water and medium-grain sand being the environments in which the majority of the bio-based materials showed the lowest degradation rates. An additional test in a small-scale electric composter with microbe technology was carried out in order to evaluate the degradation of the studied materials in an environment with controlled conditions, and results showed high values of weight loss for the majority of the bio-based materials (all above 80% weight loss) due to the high temperature that the device could reach during the composting process. Finally, a strategy for providing guidance in selecting routes for the waste management of bioplastics, depending mainly on the available infrastructure and material properties, was proposed as a result of this work. For the case of low- and medium-income countries, an Extended Producer Responsibility (EPR) policy is proposed as a provisional solution to control plastic waste pollution, which should be complemented by regulations and systems aimed at the successful introduction of bioplastics.

Compostable Packaging Waste Management—Main Barriers, Reasons, and the Potential Directions for Development

The paper aims to identify the main reasons for the low level of compostable packaging waste management and to propose potential directions for development. Based on qualitative research (individual in-depth interviews and focus group discussions using the Social Innovation Lab), these are: (1) the lack of uniform and transparent regulations regarding the planning and organization of a closed-loop system for compostable packaging, (2) insufficient communication between the private and public sectors on how to increase the use of compostable packaging, (3) poorly developed infrastructure for compostable waste recycling, and (4) a lack of financial incentives to support activities for the circular economy of composting packaging at the communal level. Moreover, the portfolio of bottom-up (initiated by consumers, educational institutions, and NGOs) and bottom-down dimension (national, regional programs) proposals are presented. The diagnosis of different view perspectives of the supply chain underlines the crucial role of stakeholder cooperation improvement.

Towards a Circular Economy of Plastics: An Evaluation of the Systematic Transition to a New Generation of Bioplastics.

Plastics have become an essential part of the modern world thanks to their appealing physical and chemical properties as well as their low production cost. The most common type of polymers used for plastic account for 90% of the total production and are made from petroleum-based nonrenewable resources. Concerns over the sustainability of the current production model and the environmental implications of traditional plastics have fueled the demand for greener formulations and alternatives. In the last decade, new plastics manufactured from renewable sources and biological processes have emerged from research and have been established as a commercially viable solution with less adverse effects. Nevertheless, economic and legislative challenges for biobased plastics hinder their widespread implementation. This review summarizes the history of plastics over the last century, including the most relevant bioplastics and production methods, the environmental impact and mitigation of the adverse effects of conventional and emerging plastics, and the regulatory landscape that renewable and recyclable bioplastics face to reach a sustainable future.

Contribution of Fermentation Technology to Building Blocks for Renewable Plastics

Large-scale worldwide production of plastics requires the use of large quantities of fossil fuels, leading to a negative impact on the environment. If the production of plastic continues to increase at the current rate, the industry will account for one fifth of global oil use by 2050. Bioplastics currently represent less than one percent of total plastic produced, but they are expected to increase in the coming years, due to rising demand. The usage of bioplastics would allow the dependence on fossil fuels to be reduced and could represent an opportunity to add some interesting functionalities to the materials. Moreover, the plastics derived from bio-based resources are more carbon-neutral and their manufacture generates a lower amount of greenhouse gasses. The substitution of conventional plastic with renewable plastic will therefore promote a more sustainable economy, society, and environment. Consequently, more and more studies have been focusing on the production of interesting bio-based building blocks for bioplastics. However, a coherent review of the contribution of fermentation technology to a more sustainable plastic production is yet to be carried out. Here, we present the recent advancement in bioplastic production and describe the possible integration of bio-based monomers as renewable precursors. Representative examples of both published and commercial fermentation processes are discussed.

Two Birds with One Stone: Bioplastics and Food Waste Anaerobic Co-Digestion

Following the BBC’s Blue Planet II nature documentary series on marine ecosystems, plastic packaging has come under public fire, with consumers demanding greener alternatives. The biodegradable properties of some bioplastics have offered a potential solution to the global challenge of plastic pollution, while enabling the capture of food waste through anaerobic digestion as a circular and energy-positive waste treatment strategy. However, despite their increasing popularity, currently bioplastics are being tested in environments that do not reflect real-life waste management scenarios. Bioplastics find their most useful, meaningful and environmentally-sound application in food packaging—why is there so little interest in addressing their anaerobic co-digestion with food waste? Here, we provide a set of recommendations to ensure future studies on bioplastic end-of-life are fit for purpose. This perspective makes the link between the environmental sustainability of bioplastics and the role of food waste anaerobic digestion as we move towards an integrated food–energy–water–waste nexus. It shines light on a novel outlook in the field of bioplastic waste management while uncovering the complexity of a successful path forward. Ultimately, this research strives to ensure that the promotion of bioplastics within a circular economy framework is supported across waste collection and treatment stages.

Plastic accumulation during COVID-19: call for another pandemic; bioplastic a step towards this challenge?

Plastic pollution has become a serious transboundary challenge to nature and human health, with estimation of reports published - predicting a twofold increase in plastic waste by 2030. However, due to the COVID-19 pandemic, the excessive use of single-use plastics (including face masks, gloves and personal protective equipment) would possibly exacerbate such forecasts. The transition towards eco-friendly alternatives like bio-based plastics and new emerging sustainable technologies would be vital to deal with future pandemics, even though the use or consumption of plastics has greatly enhanced our quality of life; it is however critical to move towards bioplastics. We cannot deny the fact that bioplastics have some challenges and shortcomings, but still, it is an ideal option for opt. The circular economy is the need of the hour for waste management. Along with all these practices, individual accountability, corporate intervention and government policy are also needed to prevent us from moving from one crisis to the next. Only through cumulative efforts, we will be able to cope up with this problem. This article collected scattered information and data about accumulation of plastic during COVID-19 worldwide. Additionally, this paper illustrates the substitution of petroleum-based plastics with bio-based plastics. Different aspects are discussed, ranging from advantages to challenges in the way of bioplastics.

Guest editorial

The SDGs include ending poverty, ending hunger, ensuring health and well-being, ensuring quality education, achieving gender equality, ensuring access to water and sanitation, ensuring affordable and clean energy, promoting decent work and economic growth, building sustainable industry, innovation and infrastructure, reducing inequalities, making sustainable cities and communities, ensuring sustainable consumption and production, taking climate action, conserving marine resources, halting biodiversity loss, promoting peace, justice and strong institutions and revitalising partnerships for sustainable development (UN, 2015). [...]despite the limited scholarly attention, the social marketing discipline has continually expanded its areas of practical application, from public health to poverty alleviation, environmental protection, healthy lifestyles and sustainable consumption and production (Truong et al., 2021). Drawing upon multiple sources of qualitative data, this study shows that when interdisciplinarity and a project-based approach are organised to create a meaningful learning environment wherein the SDGs are guiding principles, students as change agents can potentially generate beneficial and influential impacts at the individual, organisational and institutional levels. [...]the question of whether the Agenda for Sustainable Development and the SDGs can be achieved depends on the efforts and commitment of many individuals and organisations who are working to make the world a better place for all.

Disposable Food Packaging and Serving Materials-Trends and Biodegradability.

Food is an integral part of everyone's life. Disposable food serving utensils and tableware are a very convenient solution, especially when the possibility of the use of traditional dishes and cutlery is limited (e.g., takeaway meals). As a result, a whole range of products is available on the market: plates, trays, spoons, forks, knives, cups, straws, and more. Both the form of the product (adapted to the distribution and sales system) as well as its ecological aspect (biodegradability and life cycle) should be of interest to producers and consumers, especially considering the clearly growing trend of "eco-awareness". This is particularly important in the case of single-use products. The aim of the study was to present the current trends regarding disposable utensils intended for contact with food in the context of their biodegradability. This paper has summarized not only conventional polymers but also their modern alternatives gaining the attention of manufacturers and consumers of single-use products (SUPs).

Environmental impact assessment of plastic waste during the outbreak of COVID-19 and integrated strategies for its control and mitigation.

During the COVID-19 pandemic, many positive shifts have been observed in the ecosystem, with a significant decrease in the greenhouse gas emissions and air pollution. On the other hand, there were unavoidable negative shifts due to a surge in demand for plastic products such as food and groceries' delivery packaging, single-use plastics, medical and personal protective equipment to prevent transmission of COVID-19. Plastic pollution can be considered as a key environmental issue in world due to the huge footprints of plastics on natural ecosystems and public health. Herein, we presented an overview on the rise of plastic pollution during the COVID-19 pandemic. The potential sources of plastic waste during COVID-19 with its negative effects on the environment such as marine ecosystems and the global economics are highlighted. We also suggested some strategies and recommendations to tackle plastic leakages by applying feedstock recycling, sterilization, and with the use of biodegradable plastics that have become a sustainable alternative to fossil fuel plastics. Also, the importance of elevating public awareness and some recommendations to mitigate plastic generated during the pandemic has been addressed as well.

Rethinking and optimising plastic waste management under COVID-19 pandemic: Policy solutions based on redesign and reduction of single-use plastics and personal protective equipment.

Plastics have been on top of the political agenda in Europe and across the world to reduce plastic leakage and pollution. However, the COVID-19 pandemic has severely disrupted plastic reduction policies at the regional and national levels and induced significant changes in plastic waste management with potential for negative impacts in the environment and human health. This paper provides an overview of plastic policies and discusses the readjustments of these policies during the COVID-19 pandemic along with their potential environmental implications. The sudden increase in plastic waste and composition due to the COVID-19 pandemic underlines the crucial need to reinforce plastic reduction policies (and to implement them into action without delays), to scale up in innovation for sustainable and green plastics solutions, and to develop dynamic and responsive waste management systems immediately. Policy recommendations and future research directions are discussed.